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Leopold, chemistry department, university of minnesota, minneapolis, mn, usa The acid strength and related properties of fluorosulfonic acid are discussed and compared to those of perchloric acid and sulfuric acid in the context of clusters with ammonia and water. We report on the hydration of the superacid fluorosulfoni

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Geometrical parameters and wavenumbers of the normal modes of vibration of fluorosulfonic acid (fso 2 oh) and its cyclic dimer were calculated using ab initio methods. This discrepancy has not yet been resolved, though the stronger value appears preferable A far infrared and theoretical ab initio vibrational study of fluorosulfonic acid as monomer and cyclic dimer

Reacts violently with water to generate hydrofluoric acid and sulfuric acid

Reacts with active metals, including such structural metals as aluminum and iron, to release hydrogen, a flammable gas. These relative affinities are ca 10 kcal/mol weaker than threshold values (see wenthold and squires, 1995) for donors greater than ca 27 kcal/mol in free energy